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    • 专利摘要:
    The present invention relates to a cosmetic composition for the treatment of keratinous fibers, in particular human keratinous fibers such as the hair, comprising, in a cosmetically acceptable medium, one or more organosilanes, one or more cationic polymers and a particular combination of surfactants comprising anionic, nonionic and amphoteric or zwitterionic surfactants. The present invention also relates to a process for the cosmetic treatment of keratinous fibers, in particular human keratinous fibers such as the hair, using said composition. Finally, the present invention relates to the use of said composition for the cosmetic treatment of keratinous fibers, in particular human keratin fibers such as the hair, for conditioning the keratinous fibers or imparting to the keratin fibers a cosmetic care, such as detangling, remanent to shampoos.
    公开号:FR3060381A1
    申请号:FR1662659
    申请日:2016-12-16
    公开日:2018-06-22
    发明作者:Audrey CORREIA；Estelle Mathonneau
    申请人:LOreal SA；
    IPC主号:
    专利说明:

    ® FRENCH REPUBLIC
    NATIONAL INSTITUTE OF INDUSTRIAL PROPERTY © Publication number: 3,060,381 (to be used only for reproduction orders)
    ©) National registration number: 16 62 659
    COURBEVOIE © Int Cl 8 : A 61 K8 / 89 (2017.01), A 61 K8 / 84, 8/73, A 61 Q 5/12
    A1 PATENT APPLICATION
    ©) Date of filing: 16.12.16.(© Priority: (© Applicant (s): L'OREAL Société anonyme— FR. ©) Date of public availability of the request: 06.22.18 Bulletin 18/25. @ Inventor (s): CORREIA Audrey and MATHONNEAU ESTELLE. ©) List of documents cited in the preliminary search report: See the end of this booklet (© References to other related national documents: (® Holder (s): L'OREAL Société anonyme. ©) Extension request (s): (© Agent (s): CASALONGA.
    FR 3 060 381 - A1
    164 / COSMETIC COMPOSITION COMPRISING AN ORGANOSILANE, AT LEAST ONE CATIONIC POLYMER AND A PARTICULAR ASSOCIATION OF SURFACTANTS.
    The present invention relates to a cosmetic composition for the treatment of keratin fibers, in particular human keratin fibers such as the hair, comprising, in a cosmetically acceptable medium, one or more organosilanes, one or more cationic polymers and a particular combination of surfactants comprising anionic, nonionic and amphoteric or zwitterionic surfactants.
    The present invention also relates to a cosmetic treatment process for keratin fibers, in particular human keratin fibers such as the hair, using said composition.
    Finally, the present invention relates to the use of said composition for the cosmetic treatment of keratin fibers, in particular human keratin fibers such as the hair, for conditioning the keratin fibers or giving cosmetic keratin fibers, such as disentangling, remain in shampoos.
    Cosmetic composition comprising an organosilane, at least one cationic polymer and a particular combination of surfactants
    The present invention relates to a cosmetic composition for the treatment of keratin fibers, in particular human keratin fibers such as the hair, comprising, in a cosmetically acceptable medium, one or more organosilanes, one or more cationic polymers and a particular combination of surfactants comprising anionic, nonionic and amphoteric or zwitterionic surfactants.
    The present invention also relates to a cosmetic treatment process for keratin fibers using said composition.
    Finally, the present invention relates to the use of said composition for the cosmetic treatment of keratin fibers, in particular human keratin fibers such as the hair, in particular for imparting cosmetic care to the keratin fibers, such as detangling, which remains in shampoos. .
    The hair is generally damaged and weakened by the action of external atmospheric agents such as light and bad weather, and / or by mechanical or chemical treatments such as brushing, combing, dyeing, bleaching, perms and / or straighteners.
    Thus, to remedy these drawbacks, it is now customary to use hair care implying the use of care compositions which make it possible to condition the hair following these treatments in order to give them in particular shine, softness, suppleness, lightness, a natural touch as well as disentangling properties.
    These hair care compositions may for example be conditioning shampoos or compositions to be applied before or after the shampoos, and which may be in the form of gels, hair lotions or more or less thick creams.
    To improve the cosmetic properties of these compositions, it is known to introduce into the latter cosmetic agents known as conditioning agents intended mainly for repairing or limiting the harmful or undesirable effects induced by the various treatments or aggressions which undergo, more or less less repeated, the hair fibers.
    For this purpose, it has already been proposed to use, inter alia, organic silicon compounds (or organosilanes) in cosmetic care compositions, to give the hair satisfactory conditioning properties, in particular disentangling properties.
    Such compositions are for example described in patent applications FR 2 954 100 and FR 3 029 110.
    However, the care compositions described in the prior art provide conditioning and disentangling properties which do not last long enough in time. Indeed, these properties generally do not resist washing enough and tend to decrease rapidly. The residual effect of the conditioning and disentangling properties is generally limited to three shampoos.
    Thus, there is a real need to provide a cosmetic care composition for keratin fibers, in particular human keratin fibers such as the hair, which does not have the drawbacks mentioned above, that is to say which is in particular capable of providing conditioning properties which are not only satisfactory but also persistent after washing, for example persistent after at least five shampoos.
    The Applicant has discovered, surprisingly, that a composition, comprising one or more organosilanes, one or more cationic polymers and a particular combination of surfactants comprising anionic, nonionic and amphoteric or zwitterionic surfactants, made it possible to respond to the technical problems set out above.
    The present invention therefore relates to a cosmetic composition for the treatment of keratin fibers, in particular human keratin fibers such as the hair, comprising in a cosmetically acceptable medium:
    (i) one or more organosilanes, (ii) one or more cationic polymers, (iii) one or more anionic surfactants, (iv) one or more nonionic surfactants, and (v) one or more amphoteric or zwitterionic surfactants, weight ratio of the total amount of the anionic surfactant (s) to the total amount of the nonionic surfactant (s) being less than or equal to 5.
    The composition according to the invention provides a particularly satisfactory sheathing of the hair and in particular gives it softness, suppleness, straightening, lightness, volume, and a non-greasy and uncharged natural feel. This composition also provides the hair with an improved combability.
    Furthermore, the properties provided by the composition according to the invention, and in particular the disentangling properties, resist well to the various aggressions which the hair can undergo, such as light, bad weather, washing, perspiration. They are in particular persistent in shampoos, in particular after at least five shampoos.
    In addition, the composition according to the invention has good stability, especially over time.
    The present invention also relates to a process for the cosmetic treatment of keratin fibers, in particular human keratin fibers such as the hair, using said composition.
    Finally, another object of the present invention is the use of said composition for the cosmetic treatment of keratin fibers, in particular human keratin fibers such as the hair, in particular for conditioning keratin fibers, or giving keratin fibers care cosmetic, such as detangling, remanent to shampoos.
    Other objects, characteristics, aspects and advantages of the invention will appear even more clearly on reading the description and the examples which follow.
    In what follows, and unless otherwise indicated, the limits of a range of values are included in this range, in particular in the expressions "between" and "going from ... to ...".
    Furthermore, the expressions “at least one” and “at least” used in the present description are respectively equivalent to the expressions “one or more” and “greater than or equal”.
    The cosmetic composition according to the invention comprises one or more organosilanes.
    The organosilane (s) which can be used according to the invention are preferably chosen from the compounds of formula (I) and / or their hydrolysis products and / or their oligomers:
    RiSi (OR 2 ) z (R3) x (OH) y (I) in which
    - Ri is a linear or branched, saturated or unsaturated, cyclic or acyclic C1 to C22, especially C2 to C20 hydrocarbon chain, which may be substituted by one or more group (s) chosen from amine groups NH2 or NHR, R being a linear or branched C1 to C20, especially C1 to C6 alkyl, or a C3 to C40 cycloalkyl or a C6 to C30 aromatic radical; the hydroxy group; a thiol group; an aryl group, more particularly benzyl, substituted or not substituted by an NH 2 or NHR group; Ri can be interrupted by a heteroatom of oxygen, sulfur or nitrogen or a carbonyl group;
    - R2 and R3, which are identical or different, represent an alkyl group, linear or branched, comprising from 1 to 6 carbon atoms,
    - y denotes an integer ranging from 0 to 3,
    - z denotes an integer ranging from 0 to 3, and
    - x denotes an integer ranging from 0 to 2,
    - with z + x + y = 3.
    By oligomer within the meaning of the present invention is meant the polymerization products of the compounds of formula (I) comprising from 2 to 10 silicon atoms.
    Preferably, Ri is a linear or branched, saturated, C 1 to C 22, in particular C 2 to C 12, more preferably linear, hydrocarbon chain which may be substituted by one or more amine group (s) NH 2 or NHR, R being a C1 to C20 alkyl, especially C1 to C6.
    Preferably, R 2 represents an alkyl group comprising from 1 to 4 carbon atoms, more preferably a linear alkyl group comprising from 1 to 4 carbon atoms, and in particular the ethyl group.
    Preferably z varies from 1 to 3.
    Preferably, y is 0.
    Preferably, z is equal to 3.
    Even more preferably, x and y are equal to 0 and z is equal to 0.
    In one embodiment of the invention, the organosilane (s) are chosen from the compounds of formula (I) in which R 1 represents a linear alkyl group comprising from 7 to 18 carbon atoms and more particularly from 7 to 12 carbon atoms or a C 1 -C 6 aminoalkyl group, preferably C 2 -C 4 .
    Particularly preferably in this embodiment, R 1 represents an octyl group.
    In another embodiment of the invention, the organosilane (s) are chosen from the compounds of formula (I) in which R 1 is a C 1 to C 22 hydrocarbon chain, linear or branched, saturated or unsaturated, substituted by one or more NH 2 or NHR amine group (s), R being a linear or branched C1 to C20, preferably C1 to Ce, or a C3 to C40 cycloalkyl or a Ce to C30 aromatic.
    In a particularly preferred manner in this other embodiment, R 1 represents a C1 to C6, more preferably C2 to C4 aminoalkyl group.
    Preferably, the organosilane (s) which can be used according to the invention are chosen from octyltriethoxysilane (OTES), dodecyltriethoxysilane, octadecyltriethoxysilane, hexadecyltriethoxysilane, 3-aminopropyltriethoxysilane (APTES), (AETES), 2-aminoethyl) -3le 2-aminoethyltriethoxy silane aminopropylmethyldiethoxysilane, aminopropyltriethoxysilane, 3- (maminophenoxy) propyltrimethoxysilane, paminophenyltrimethoxysilane, N- (2 aminoethylaminomethyl) phenethyltrimethilanes; and more particularly the organosilane (s) are chosen from octyltriethoxysilane (OTES), 3-aminopropyltriethoxysilane (APTES), their hydrolysis products, their oligomers and their mixtures.
    In a particularly preferred manner, the organosilane is 3 aminopropyltriethoxysilane (APTES).
    The organosilanes used in the composition of the invention, in particular those comprising a basic function, can be neutralized, partially or completely, in order to improve their solubility in water. In particular, the neutralizing agent can be chosen from organic or mineral acids, such as citric acid, tartaric acid, lactic acid and hydrochloric acid.
    Preferably, the organosilane (s) which can be used according to the invention, optionally neutralized, are soluble in water and in particular soluble at the concentration of 2% by weight, better at the concentration of 5% by weight and even better at the concentration of 10% by weight in water at a temperature of 25 ° C, and at atmospheric pressure (1 atm.). By soluble is meant the formation of a single macroscopic phase.
    The organosilane (s) generally represent from 0.1 to 15% by weight, preferably from 0.5 to 10% by weight, and more preferably from 1 to 8% by weight, relative to the total weight of the composition according to the invention.
    As indicated above, the cosmetic composition according to the invention also comprises one or more cationic polymers (ii).
    Within the meaning of the present invention, the expression “cationic polymer” designates any polymer containing cationic groups and / or groups which can be ionized into cationic groups.
    The cationic polymer (s) (ii) present in the composition according to the invention can be chosen from all those already known per se as improving the cosmetic properties of the hair, namely in particular those described in patent application EP-A-337 354 and in French patents FR-2 270 846, 2 383 660, 2 598 61 1, 2 470 596 and 2 519 863.
    The cationic polymer (s) (ii) used generally have a number-average molecular mass of between 500 and 5,106 g / mol approximately, and preferably between 103 and 3,106 g / mol approximately.
    Among the cationic polymers, mention may more particularly be made of polymers of the polyamine, polyaminoamide and quaternary polyammonium type.
    These are known products. They are described in particular in French patents 2,505,348 or 2,542,997.
    The cationic polymers (ii) used in the cosmetic composition according to the invention can be chosen from:
    (1) Homopolymers or copolymers derived from acrylic or methacrylic esters or amides and comprising at least one of the units of formulas (II), (III), (IV) or (V):
    CH:
    R,
    X
    F% (ΠΙ)
    CH
    CH:
    R, (IV)
    O =
    NH
    I
    AT
    I
    (V) in which:
    R3, identical or different, denote a hydrogen atom or a CH3 radical;
    A, identical or different, represent an alkyl group, linear or branched, from 1 to 6 carbon atoms, preferably 2 or 3 carbon atoms or a hydroxyalkyl group from 1 to 4 carbon atoms;
    R4, R5, R6, identical or different, represent an alkyl group having from 1 to 18 carbon atoms or a benzyl radical and preferably an alkyl group having from 1 to 6 carbon atoms;
    Ri and R2, identical or different, represent a hydrogen atom or an alkyl group having from 1 to 6 carbon atoms and preferably a methyl or ethyl radical;
    X denotes an anion derived from a mineral or organic acid such as a methosulfate anion or a halide such as chloride or bromide.
    Mention may in particular be made of the homopolymer of ethyl trimethyl ammonium methacrylate chloride.
    The polymers of family (1) may also contain one or more units deriving from comonomers which can be chosen from the family of acrylamides, methacrylamides, diacetones, acrylamides, acrylamides and methacrylamides substituted on nitrogen by lower alkyls (C1-C4) , acrylic or methacrylic acids or their esters, vinyllactams such as vinylpyrrolidone or vinylcaprolactam, vinyl esters.
    Thus, among these polymers of family (1), there may be mentioned:
    - copolymers of acrylamide and of dimethyl-amino-ethyl methacrylate quaternized with dimethyl sulphate or with a dimethyl halide, such as that sold under the name HERCOFLOC by the company HERCULES, copolymers of acrylamide and methacryloyloxy chloride- ethyl-trimethyl-ammonium described for example in patent application EP-A-080976 and sold under the name BINA QUAT P 100 by the company CIBA GEIGY, the copolymer of acrylamide and methacryloyloxy-ethyl-trimethyl-ammonium methosulfate sold under the name RETEN by the company HERCULES,
    - vinylpyrrolidone / acrylate or methacrylate of dialkylaminoalkyl copolymers, quaternized or not, such as the products sold under the name "GAFQUAT" by the company ISP, for example "GAFQUAT 734" or "GAFQUAT 755" or else the products called "COPOLYMER 845, 958 and 937 ". These polymers are described in detail in French patents 2,077,143 and 2,393,573,
    - dimethyl amino ethyl methacrylate / vinylcaprolactam / vinylpyrrolidone terpolymers such as the product sold under the name GAFFIX VC 713 by the company ISP,
    - vinylpyrrolidone / methacrylamidopropyl dimethylamine copolymers sold in particular under the name STYLEZE CC 10 by ISP,
    - quaternized vinylpyrrolidone / dimethyl-amino-propyl vinylpyrrolidone / methacrylamide copolymers such as the product sold under the name "GAFQUAT HS 100" by the company ISP, ίο
    - crosslinked polymers of methacryloyloxyalkyl (CiC4) trialkyl (Ci-C4) ammonium salts such as the polymers obtained by homopolymerization of dimethylaminoethylmethacrylate quaternized with methyl chloride, or by copolymerization of acrylamide with dimethylaminoethylmethacrylate quaternized with methyl chloride , homo or copolymerization being followed by crosslinking with an olefinically unsaturated compound, in particular methylene bis acrylamide. It is more particularly possible to use a crosslinked acrylamide / methacryloyloxyethyltrimethylammonium chloride copolymer (20/80 by weight) in the form of a dispersion containing 50% by weight of said copolymer in mineral oil. This dispersion is marketed under the name of "SALCARE® SC 92" by the company CIBA. It is also possible to use a crosslinked homopolymer of methacryloyloxyethyl trimethylammonium chloride containing approximately 50% by weight of the homopolymer in mineral oil or in a liquid ester. These dispersions are marketed under the names of “SALCARE® SC 95” and “SALCARE® SC 96” by the company CIBA.
    (2) Derivatives of cellulose ethers comprising quaternary ammonium groups such as those described in French patent 1 492 597, and in particular the polymers marketed under the names "UCARE POLYMER JR" (JR 400, JR 125, JR 30M ) or "LR" (LR 400, LR 30M) by the company AMERCHOL. These polymers are also defined in the CTFA dictionary as quaternary ammoniums of hydroxyethylcellulose having reacted with an epoxide substituted by a trimethylammonium group.
    (3) Cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer, and described in particular in US Patent 4,131,576, such as hydroxyalkyl celluloses, such as grafted hydroxymethyl-, hydroxyethyl- or hydroxypropyl celluloses in particular with a salt of methacryloylethyl trimethylammonium, of methacrylmidopropyl trimethylammonium, of dimethyldi al lyl ammonium.
    The marketed products meeting this definition are more particularly the products sold under the name "Celquat L 200" and "Celquat H 100" by the National Starch Company.
    (4) Cationic guar gums, in particular those described more particularly in US patents 3,589,578 and 4,031,307 such as guar gums containing cationic trialkylammonium groups. Guar gums modified with a salt (eg chloride) of 2,3-epoxypropyl trimethylammonium are used, for example.
    Such products are marketed in particular under the trade names of JAGUAR C13 S, JAGUAR C 15, JAGUAR C 17 or JAGUAR Cl62 by the company RHODIA.
    (5) Polymers consisting of piperazinyl units and divalent alkylene or hydroxyalkylene radicals with straight or branched chains, optionally interrupted by oxygen, sulfur, nitrogen atoms or by aromatic or heterocyclic rings, as well as the products of oxidation and / or quaternization of these polymers. Such polymers are described in particular in French patents 2,162,025 and 2,280,361.
    (6) Water-soluble polyaminoamides prepared in particular by polycondensation of an acidic compound with a polyamine; these polyaminoamides can be crosslinked with an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a bis-unsaturated derivative, a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, a bis-halide of alkyl or also with an oligomer resulting from the reaction of a bifunctional compound reactive with a bis-halohydrin, a bis-azetidinium, a bishaloacyldiamine, an alkyl bis-halide, a epilhalohydrin, a diepoxide or a bis-unsaturated derivative; the crosslinking agent being used in proportions ranging from 0.025 to 0.35 mol per amine group of the polyaminoamide; these polyaminoamides can be alkylated or if they contain one or more tertiary amine functions, quaternized. Such polymers are described in particular in French patents 2,252,840 and 2,368,508.
    (7) Polyaminoamide derivatives resulting from the condensation of polyalkylene polyamines with polycarboxylic acids followed by alkylation by bifunctional agents. Mention may be made, for example, of the adipic acid-diacoylaminohydroxyalkoyldialoylene triamine polymers in which the alkyl radical contains from 1 to 4 carbon atoms and preferably denotes the methyl, ethyl and propyl radicals. Such polymers are described in particular in French patent 1,583,363.
    Among these derivatives, there may be mentioned more particularly the adipic acid / dimethylaminohydroxypropyl / diethylene triamine polymers sold under the name "Cartaretine F, F4 or F8" by the company Sandoz.
    (8) The polymers obtained by reaction of a polyalkylene polyamine comprising two primary amine groups and at least one secondary amine group with a dicarboxylic acid chosen from diglycolic acid and saturated aliphatic dicarboxylic acids having from 3 to 8 carbon atoms; the molar ratio between the polyalkylene polylamine and the dicarboxylic acid being between 0.8: 1 and 1.4: 1 and the resulting polyaminoamide being reacted with epichlorohydrin in a molar ratio of epichlorohydrin with respect to the group secondary amine of the polyaminoamide of between 0.5: 1 and 1.8: 1. Such polymers are described in particular in American patents 3,227,615 and 2,961,347.
    Polymers of this type are in particular sold under the name "Hercosett 57" by the company Hercules Inc. or else under the name of "PD 170" or "Delsette 101" by the company Hercules in the case of the adipic acid copolymer / epoxypropyl / diethylene-triamine.
    (9) Cyclopolymers of alkyl diallyl amine or dialkyl diallyl ammonium such as homopolymers or copolymers comprising, as main constituent of the chain, units corresponding to formulas (VI) or (VII):
    CH
    H.
    (VI)
    / (ÇH 2 ) k
    Ç (R g ) - CH r
    R.
    '7
    CH.
    (VII) formulas in which:
    k and t are equal to 0 or 1, the sum k + t being equal to 1;
    R9 denotes a hydrogen atom or a methyl radical;
    R7 and Rs, independently of one another, denote an alkyl group having from 1 to 6 carbon atoms, a hydroxyalkyl group in which the alkyl group preferably has 1 to 5 carbon atoms, a lower amidoalkyl group (C1 -C4), or R7 and Rs can denote jointly with the nitrogen atom to which they are attached, heterocyclic groups, such as piperidinyl or morpholinyl; R7 and Rs, independently of one another, preferably denote an alkyl group having from 1 to 4 carbon atoms;
    Y is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, phosphate. These polymers are described in particular in French patent 2,080,759 and in its certificate of addition 2,190,406.
    Among the polymers defined above, there may be mentioned more particularly the homopolymer of dimethyldiallylammonium chloride sold under the name "Merquat 100" by the company NALCO (and its low molecular weight average counterparts) and the chloride chloride copolymers diallyldimethylammonium and acrylamide marketed under the name "MERQUAT 550", "MERQUAT 7SPR".
    (10) quaternary diammonium polymers containing recurring units corresponding to the following formula (VIII):

    -N + -A 1 -N + -B, -
    I 1 © XR 13 x (VIII) in which:
    Rio, Ru, R12 and R13, identical or different, represent aliphatic, alicyclic, or arylaliphatic radicals containing from 1 to 6 carbon atoms or lower hydroxyalkylaliphatic radicals, or else Rio, Ru, R12 and R13, together or separately, constitute with the nitrogen atoms to which they are attached heterocycles optionally containing a second heteroatom other than nitrogen or else Rio, R11, R12 and R13 represent a linear or branched C1-C6 alkyl radical substituted by a nitrile, ester group, acyl, amide or -CO-O-R14-D or -CO-NH-R14-D where R14 is an alkylene and D is a quaternary ammonium group;
    Ai and Bi represent polymethylenic groups containing from 2 to 8 carbon atoms which may be linear or branched, saturated or unsaturated, and which may contain, linked to or intercalated in the main chain, one or more aromatic rings, or one or more atoms of oxygen, sulfur or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups, and
    X denotes an anion derived from a mineral or organic acid;
    Ai, Rio and R12 can form with the two nitrogen atoms to which they are attached a piperazine ring; moreover, if Ai denotes a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene radical, Bi can also denote a group - (CH 2 ) n-CO-D-OC- (CH 2 ) n- in which D denotes:
    a) a glycol residue of formula: -O-Z-O-, where Z denotes a linear or branched hydrocarbon radical or a group corresponding to one of the following formulas:
    - (CH 2 -CH2-O) x -CH2-CH 2 - [CH 2 -CH (CH 3 ) -O] y -CH 2 -CH (CH 3 ) where x and y denote an integer from 1 to 4 , representing a defined and unique degree of polymerization or any number from 1 to 4 representing an average degree of polymerization;
    b) a bis-secondary diamine residue such as a piperazine derivative;
    c) a bis-primary diamine residue of formula: -NH-Y-NH-, where Y denotes a linear or branched hydrocarbon radical, or else the bivalent radical
    -CH2-CH2-S-S-CH2-CH2-;
    d) a ureylene group of formula: -NH-CO-NH-.
    Preferably, X is an anion such as chloride or bromide.
    These polymers have a number average molecular weight generally between 1000 and 100,000.
    Polymers of this type are described in particular in French patents 2,320,330, 2,270,846, 2,316,271, 2,336,434 and
    2,413,907 and US patents 2,273,780, 2,375,853, 2,388,614,
    2.454.547, 3.206.462, 2.261.002, 2.271.378, 3.874.870, 4.001.432, 3.929.990, 3.966.904, 4.005.193, 4.025.617, 4.025.627, 4.025.653, 4.026. 945 and 4,027,020.
    It is possible to use more particularly the polymers which consist of recurring units corresponding to the following formula (IX):
    -N- (CH 2 ) n —N- (CH 2 ) -

    (IX) in which Rio, Ru, R12 and R13, identical or different, denote an alkyl or hydroxyalkyl radical having from 1 to 4 carbon atoms approximately, n and p are whole numbers varying from 2 to 8 approximately and, X is an anion derived from a mineral or organic acid. Mention may in particular be made of MEXOMERE PO sold by the company CHIMEX.
    (11) Quaternary polyammoniums made up of recurring units of formula (X):
    CH, i +
    -ΜΙ
    CH, (CH 2 ) -NH-CO-D-NH- (CH 2 )
    CH, 1 +
    ΜΙ
    CH, (CH,), - O - (CH,), (X) in which p denotes an integer varying from 1 to 6 approximately, D may be zero or may represent a group - (CH2) rCO- in which r denotes a number equal to 4 or 7, X is an anion;
    Such polymers can be prepared according to the methods described in U.S. Pat. Nos. 4,157,388, 4,702,906, 4,719,282. They are described in particular in patent application EP-A-122 324.
    Among them, there may be mentioned, for example, the products "Mirapol A 15", "Mirapol ADI", "Mirapol AZ1" and "Mirapol 175" sold by the company Miranol.
    (12) Quaternary polymers of vinylpyrrolidone and of vinylimidazole such as for example the products marketed under the names Luviquat FC 905, FC 550 and FC 370 by the company B.A.S.F. These polymers can also include other monomers such as diallyldialkylammonium halides. Mention may be made, in particular, of the product sold under the name Luviquat Sensation by the company B.A.S.F.
    (13) Cationic polyamines such as Polyquart H sold by HENKEL, referenced under the name of “POLYETHYLENEGLYCOL (15) TALLOW POLYAMINE” in the CTFA dictionary, or polyamines of oxyethylenated coconut (15 OE).
    Other cationic polymers which can be used in the context of the invention are polyalkyleneimines, in particular polyethyleneimines, polymers containing vinylpyridine or vinylpyridinium units, condensates of polyamines and epichlorohydrin, quaternary polyuretylenes and chitin derivatives.
    Among all the cationic polymers capable of being used in the context of the present invention, it is preferred to use the polymers of families (1), (2), (3), (4), (9), (10) and (12), more particularly the polymers of families (2) and (9), and better among the polymers of family (9).
    Even more preferably, the cationic polymer or polymers used in the cosmetic composition according to the invention are chosen from homopolymers of dimethyldiallylammonium chloride and copolymers of diallyldimethylammonium chloride and acrylamide, and even more preferably the cationic polymer is the homopolymer dimethyldiallylammonium chloride (polyquaternium-6).
    The cationic polymer (s) generally represent from 0.01 to 10% by weight, preferably from 0.1 to 8% by weight, more preferably from 0.2% to 5% by weight, and even better still from 0.3 to 3.5% by weight, relative to the total weight of the composition according to the invention.
    Preferably, the weight ratio in the cosmetic composition according to the invention between the organosilane (s) and the cationic polymer (s) varies from 0.1 to 20, more preferably from 0.5 to 15.
    As indicated above, the cosmetic composition according to the invention also comprises one or more anionic surfactants.
    For the purposes of the present invention, the term “anionic surfactant” means a surfactant comprising only, as ionic or ionizable groups, anionic groups. These anionic groups are preferably chosen from the CO2H, CO 2 -, SO3H, SO 3 -, OSO3H, OSO3 groups; H2PO3, HPO3; PO 3 2 , H2PO2, HPO 2 , PO 2 2 , POH, PO.
    Preferably, the anionic surfactant (s) used in the composition according to the invention are chosen from anionic surfactants comprising in their structure one or more sulphate and / or sulphonate and / or phosphate and / or carboxylate groups, and / or their mixtures, preferably the anionic surfactant (s) are chosen from anionic surfactants comprising in their structure one or more sulphate and / or sulphonate and / or phosphate groups, the anionic alkyl ether carboxylic surfactants and / or their mixtures.
    Preferably, the composition according to the invention comprises one or more anionic alkyl ether carboxylic surfactants.
    In a variant of the invention, the composition according to the invention comprises a mixture of anionic surfactants and in particular one or more anionic surfactants comprising in their structure one or more sulfate and / or sulfonate and / or phosphate groups and one or more anionic surfactants alkyl ether carboxylic.
    The anionic surfactant (s) comprising in their structure one or more sulphate and / or sulphonate and / or phosphate groups can be oxyethylenated and / or oxypropylenated. The total average number of ethylene oxide (EO) and / or propylene oxide (OP) groups can then vary from 1 to 50 and in particular from 2 to 10.
    The anionic surfactant (s) comprising in their structure one or more sulphate and / or sulphonate and / or phosphate groups can be chosen from alkyl sulphates, alkylamidosulphates, alkylethersulphates, alkylamidoethersulphates, alkylarylethersulphates, alkylethersulphosuccinates, acylisethionates, methyl acyl taurates, sulfonate olefins, and their salts; the alkyl or acyl group of all these different compounds preferably comprising from 8 to 24 carbon atoms, and the aryl group preferably denoting a phenyl or benzyl group.
    Among the anionic surfactants comprising in their structure one or more sulphate and / or sulphonate and / or phosphate groups, it is preferred to use one or more sulphate anionic surfactants, preferably chosen from C8-C14 alkyl ether sulphates and more particularly those of C12- C14, and / or one or more anionic sulfonate surfactants chosen from sulfonate olefins.
    Preferably, the anionic surfactant (s) comprising in their structure one or more sulphate and / or sulphonate and / or phosphate groups are in the form of salts, and in particular of alkali metal salts, in particular sodium salts, ammonium salts, amine salts including amino alcohol salts, and / or magnesium salts. These salts preferably comprise from 2 to 5 groups of ethylene oxide.
    More preferably used among these are sodium, triethanolamine, magnesium or ammonium (Ci2-Ci4) alkyl sulfates, and / or sodium, ammonium or of magnesium, oxyethylenated, for example with 1 or 2.2 moles of ethylene oxide or sodium olefin sulfonates.
    Better still, the surfactant (s) comprising in their structure one or more sulphate and / or sulphonate and / or phosphate groups are chosen from sodium, ammonium or magnesium alkyl (Ci2-Ci4) ethersulphates, oxyethylenated at 2.2 moles of ethylene oxide, as marketed under the name TEXAPON N702 by the company COGNIS.
    Among the anionic surfactants comprising in their structure one or more sulphate and / or sulphonate and / or phosphate groups, it is preferred to use the sodium or ammonium lauryl ether sulphates or the sodium sulphonate olefins.
    The anionic alkyl ether carboxylic surfactant (s) capable of being used according to the invention preferably comprise a C6-C24 alkyl chain.
    The anionic alkyl ether carboxylic anionic surfactant (s) can be chosen, alone or as a mixture, from:
    - alkyl (C6-C 24 ) ether carboxylic acids,
    - alkyl (C6-C 24 ) aryl ether carboxylic acids,
    - alkyl (C6-C 24 ) amido ether carboxylic acids,
    - and their salts.
    The anionic alkyl ether carboxylic anionic surfactant (s) may be oxyalkylenated, preferably oxyethylenated and / or oxypropylenated. The total average number of alkylene oxide groups then preferably varies from 2 to 50, in particular from 2 to 24, and better still from 2 to 15.
    When the anionic alkyl ether carboxylic anionic surfactant (s) are oxyalkylenated, they preferably comprise from 2 to 50 alkylene oxide groups, and in particular from 2 to 50 ethylene oxide (EO) groups.
    Preferably, the anionic alkyl ether carboxylic anionic surfactant (s) are neutralized by one or more salts. The salts are in particular chosen from alkaline salts, in particular sodium salts, ammonium salts, amine salts, including amino alcohol salts, such as triethanolamine or monoethanolamine salts, and magnesium salts.
    More preferably, polyethoxylated anionic carboxylic surfactants are used which correspond to the following formula (XI):
    Ri (OC 2 H 4 ) nOCH 2 COOA (XI) in which:
    R 1 represents a group or a mixture of alkyl or alkenyl groups, linear or branched, in Cs-C 2 2, an alkyl group (CsCsOphenyl, a group R2CONH-CH2-CH2- with R 2 denoting an alkyl or alkenyl group, linear or branched, in C11-C21, n is an integer or decimal number (average value) which can vary from 2 to 24 and preferably from 2 to 15,
    A denotes H, NH4, Na, K, Li, Mg or a monoethanolamine or triethanolamine residue. It is also possible to use mixtures of compounds of formula (XI), in particular mixtures in which the groups R 1 are different.
    Preferably, Ri denotes a group or a mixture of groups chosen from C12-C14 alkyl, cocoyl, oleyl, nonylphenyl, and octylphenyl groups; A denotes a hydrogen or sodium atom; and n varies from 2 to 20, and preferably 2 to 10.
    Even more preferably, compounds of formula (XI) are used in which R 1 denotes a C 12 alkyl group; A denotes a hydrogen or sodium atom; and n ranges from 2 to 10.
    Among the commercial products, it is possible to use preferably the products sold by the company KAO under the names:
    ΑΚΥΡΟ® NP 70 (Ri = nonylphenyl, n = 7, A = H)
    ΑΚΥΡΟ® NP 40 (Ri = nonylphenyl, n = 4, A = H)
    AKYPO®OP 40 (Ri = octylphenyl, n = 4, A = H)
    ΑΚΥΡΟ® OP 80 (Ri = octylphenyl, n = 8, A = H)
    ΑΚΥΡΟ® OP 190 (Ri = octylphenyl, n = 19, A = H)
    ΑΚΥΡΟ® RLM 38 (Ri = C12-C14 alkyl, n = 4, A = H)
    ΑΚΥΡΟ® RLM 38 NV (Ri = C12-C14 alkyl, n = 4, A = Na)
    ΑΚΥΡΟ® RLM 45 CA (Ri = C12-C14 alkyl, n = 4.5, A = H)
    ΑΚΥΡΟ® RLM 45 NV (Ri = C12-C14 alkyl, n = 4.5, A = Na)
    ΑΚΥΡΟ® RLM 100 (Ri = C12-C14 alkyl, n = 10, A = H)
    ΑΚΥΡΟ® RLM 100 NV (Ri = C12-C14 alkyl, n = 10, A = Na)
    ΑΚΥΡΟ® RLM 130 (Ri = C12-C14 alkyl, n = 13, A = H)
    ΑΚΥΡΟ® RLM 160 NV (Ri = C12-C14 alkyl, n = 16, A = Na), or by the company SANDOZ under the names:
    SANDOPAN DTC-Acid (RI = C13 alkyl, n = 6, A = H) SANDOPAN DTC (RI = C13 alkyl, n = 6, A = Na)
    SANDOPAN LS 24 (RI = C12-C14 alkyl, n = 12, A = Na)
    SANDOPAN JA 36 (RI = C13 alkyl, n = 18, A = H), and more particularly, the products sold under the following names:
    ΑΚΥΡΟ® RLM 45 (INCI: Laureth-5 carboxylic acid)
    AKYPO®RLM 100
    ΑΚΥΡΟ® RLM 38.
    Among the anionic alkyl ether carboxylic surfactants, sodium lauryl ether acids or sodium lauryl ether carboxylates are preferably used.
    Preferably, the anionic surfactants are chosen from sulfated anionic surfactants, chosen in particular from Cs-Cu alkyl ether sulfates, and alkyl ether carboxylic surfactants.
    Preferably, the composition according to the invention comprises one or more alkyl ether carboxylic surfactants corresponding to formula (XI).
    In a variant of the invention, the composition according to the invention comprises a mixture of anionic sulfated surfactants, chosen in particular from C 1 -C 4 alkyl ether sulfates and more particularly those of C 12 -C 14, and alkyl ether carboxylic surfactants corresponding to formula (XI) as described above.
    The anionic surfactant (s) generally represent from 1 to 20% by weight, preferably from 2 to 18% by weight, more preferably from 4 to 15% by weight, relative to the total weight of the composition according to the invention.
    As indicated above, the cosmetic composition according to the invention also comprises one or more nonionic surfactants.
    The nonionic surfactant (s) present in the composition according to the invention are described for example in "Handbook of Surfactants" by M.R. PORTER, Blackie & Son editions (Glasgow and London), 1991, pp 116-178.
    By way of examples of nonionic surfactants, mention may be made of the following nonionic surfactants:
    - oxyalkylenated (C8-C 24) alkyl phenols;
    - Cs to C40 alcohols, saturated or unsaturated, linear or branched, oxyalkylenated or glycerolated, they preferably contain one or two fatty chains;
    - fatty acid amides of Cs to C30, saturated or not, linear or branched, oxyalkylenated;
    - esters of Cs to C30 acids, saturated or not, linear or branched, and of polyethylene glycols;
    - esters of Cs to C30 acids, saturated or unsaturated, linear or branched, and of sorbitol, preferably oxyethylenated;
    - fatty acid and sucrose esters, alkyl (C8-C3o) (poly) glucosides, alkenyl (C8C3o) (poly) glucosides, optionally oxyalkylenated (0 to 10 oxyalkylenated units) and comprising from 1 to 15 glucose units , alkyl esters (C8-C3o) (poly) glucosides,
    - oxyethylenated vegetable oils, saturated or not;
    ethylene oxide and / or propylene oxide condensates;
    - N-alkyl (C8-C3o) glucamine and N-acyl (C8C3o) -methylglucamine derivatives;
    - aldobionamides;
    - amine oxides;
    - oxyethylenated and / or oxypropylenated silicones,
    - and their mixtures.
    The oxyalkylenated units are more particularly oxyethylenated, oxypropylenated units, or their combination, preferably oxyethylenated.
    The number of moles of ethylene oxide and / or propylene preferably ranges from 1 to 250, more particularly from 2 to 100; better from 2 to 50; the number of moles of glycerol ranges in particular from 1 to 50, better still from 1 to 10.
    Advantageously, the nonionic surfactants according to the invention do not comprise oxypropylenated units.
    By way of example of nonionic glycerolated surfactants, use is preferably made of Cs to C40 alcohols, mono- or polyglycerolated, comprising from 1 to 50 moles of glycerol, preferably from 1 to 10 moles of glycerol.
    By way of example of compounds of this type, there may be mentioned, lauric alcohol with 4 moles of glycerol (name INCI POLYGLYCERYL-4 LAURYL ETHER), lauric alcohol with 1.5 moles of glycerol, oleic alcohol with 4 moles of glycerol (INCI name: POLYGLYCERYL-4 OLEYL ETHER), oleic alcohol with 2 moles of glycerol (INCI name: POLYGLYCERYL-2 OLEYL ETHER), cetearyl alcohol with 2 moles of glycerol, cetearyl alcohol to 6 moles of glycerol, oleocetyl alcohol to 6 moles of glycerol, and octadecanol to 6 moles of glycerol.
    Among the glycerolated alcohols, it is more particularly preferred to use Cs to Cio alcohol to one mole of glycerol, Cio to C12 alcohol to one mole of glycerol and C12 alcohol to 1.5 moles of glycerol.
    The nonionic surfactant (s) used in the composition according to the invention are preferably chosen from:
    - Cs to C40 alcohols, saturated or unsaturated, linear or branched, oxyethylenated comprising from 1 to 100 moles of ethylene oxide, preferably from 2 to 50, more particularly from 2 to 40 moles of ethylene oxide ; they preferably comprise one or two fatty chains;
    - oxyethylenated vegetable oils, saturated or not, comprising from 1 to 100 moles of ethylene oxide, preferably from 2 to 50;
    (C8-C3o) alkyl (poly) glucosides, optionally oxyalkylenated, preferably from 0 to 10 moles of ethylene oxide, and comprising 1 to 15 glucose units;
    - Cs to C40 alcohols, mono- or polyglycerolated, comprising from 1 to 50 moles of glycerol, preferably from 1 to 10 moles of glycerol;
    - fatty acid amides of Cs to C30, saturated or unsaturated, linear or branched, oxyalkylenated;
    - esters of Cs to C30 acids, saturated or not, linear or branched, and of polyethylene glycols;
    - esters of Cs to C30 acids, saturated or not, linear or branched, and of sorbitol, preferably oxyethylenated;
    - and their mixtures.
    More preferably, the nonionic surfactant (s) used in the composition according to the invention are chosen from:
    - C 8 to C 4 o alcohols, saturated or unsaturated, linear or branched, oxyethylenated comprising from 1 to 100 moles of ethylene oxide, preferably from 2 to 50, more particularly from 2 to 40 moles of oxide ethylene and having one or two fatty chains;
    - esters of C 8 to C 30 acids, saturated or not, linear or branched, and of sorbitol, preferably oxyethylenated; even more preferably, the nonionic surfactant (s) are chosen from:
    - C 8 to C 4 o alcohols, saturated or unsaturated, linear or branched, oxyethylenated comprising from 1 to 100 moles of ethylene oxide, preferably from 2 to 50, more particularly from 2 to 40 moles of oxide ethylene and having one or two fatty chains.
    Even more preferably, the nonionic surfactants are chosen from C 8 -C 4 alcohols, saturated or not, linear or branched, oxyethylenated comprising from 1 to 100 moles of ethylene oxide, preferably from 2 to 50 , more particularly from 2 to 40 moles, or even from 3 to 20 moles of ethylene oxide and comprising at least one C 8 -C 20 alkyl chain, in particular Cio-Cis; in particular lauric alcohol with 4 moles of ethylene oxide (name INCI LAURETH-4) and lauric alcohol with 12 moles of ethylene oxide (name INCI: LAURETH-12), and acid esters C 8 to C 30, saturated or unsaturated, linear or branched, and preferably oxyethylenated sorbitol.
    Better still, the nonionic surfactant (s) are chosen from C 8 to C 4 o alcohols, saturated or not, linear or branched, oxyethylenated comprising from 1 to 100 moles of ethylene oxide, preferably from 2 to 50, more particularly from 2 to 40 moles, or even from 3 to 20 moles of ethylene oxide and comprising at least one C 8 -C 20 alkyl chain, in particular Cio-Cis; in particular lauric alcohol with 4 moles of ethylene oxide (INCI name: LAURETH-4) and lauric alcohol with 12 moles of ethylene oxide (INCI name: LAURETH-12).
    Preferably, the nonionic surfactant (s) generally represent 2 to 20% by weight, preferably 3 to 15% by weight, more preferably 4 to 12% by weight relative to the total weight of the composition according to the invention .
    As indicated previously, the weight ratio of the total amount of the anionic surfactant (s) to the total amount of the nonionic surfactant (s) is less than or equal to 5.
    Preferably, this weight ratio goes from 0.1 to 5, more preferably goes from 0.2 to 4.5, even more preferably goes from 0.3 to 4, better goes from 0.35 to 3, even better from 0 , 4 to 2.5.
    As indicated above, the cosmetic composition according to the invention also comprises one or more amphoteric or zwitterionic surfactants.
    In particular, the amphoteric or zwitterionic surfactant (s), preferably non-silicone, used in the composition according to the present invention, can in particular be derivatives of secondary or tertiary aliphatic amines, optionally quaternized, in which the aliphatic group is a straight chain or branched comprising from 8 to 22 carbon atoms, said amine derivatives containing at least one anionic group such as, for example, a carboxylate, sulfonate, sulfate, phosphate or phosphonate group.
    Mention may be made in particular of (C8-C2o) alkyl betaines, (C8-C2o) alkyl sulfobetaines, (C8-C2o) amidoalkyl (C3C8) alkyl betaines and (C8-C2o) -amidalkyl (C6-C8) alkyls sulfobetaines.
    Among the derivatives of secondary or tertiary aliphatic amines, optionally quaternized which can be used, as defined above, mention may also be made of the following compounds of respective structures (XII) and (XIII):
    R a -CONHCH2CH2-N + (Rb) (Rc) -CH 2 COO ·, M + , X '(XII)
    Formula in which:
    - R a represents a C10 to C30 alkyl or alkenyl group derived from an acid R a COOH, preferably present in hydrolyzed coconut oil, a heptyl, nonyl or undecyl group;
    - Rb represents a beta-hydroxyethyl group; and
    - R c represents a carboxymethyl group;
    M + represents a cationic counter ion derived from an alkaline, alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine, and
    - X represents an organic or inorganic anionic counter ion, such as that chosen from halides, acetates, phosphates, nitrates, (Ci-C4) alkyl sulfates, (Ci-C4) alkyl - or (CiC4) aryl-sulfonates alkyl, in particular methyl sulphate and ethyl sulphate; or else M + and X are absent;
    R a -CONHCH 2 CH 2 -N (B) (B ') (XIII)
    Formula in which:
    - B represents the group -CH 2 CH 2 OX ';
    - B 'represents the group - (CH 2 ) Z Y', with z = 1 or 2;
    - X 'represents the group -CH 2 COOH, -CH 2 -COOZ', -CH 2 CH 2 COOH, CH 2 CH 2 -COOZ ', or a hydrogen atom;
    - Y 'represents the group -COOH, -COOZ', -CH 2 CH (OH) SO 3 H or the group CH 2 CH (OH) SO 3 -Z ';
    - Z ’represents a cationic counter ion from an alkali or alkaline earth metal, such as sodium, an ammonium ion or an ion from an organic amine;
    R a ′ represents a Cio to C 3 o alkyl or alkenyl group of an acid R a -COOH preferably present in coconut oil or in hydrolysed linseed oil, an alkyl group, in particular C17 and its iso form, an unsaturated C17 group.
    These compounds are classified in the CTFA dictionary, 5th edition, 1993, under the names disodium cocoamphodiacetate, disodium lauroamphodiacetate, disodium caprylamphodiacetate, disodium capryloamphodiacetate, disodium cocoamphodipropionate, disodium lauroamphodipropionate, capryl disodium propopropate lauroamphodipropionic, cocoamphodipropionic acid.
    By way of example, mention may be made of cocoamphodiacetate marketed by the company RHODIA under the trade name MIRANOL® C2M concentrate.
    It is also possible to use compounds of formula (XIV);
    R a ”-NHCH (Y”) - (CH2) nCONH (CH 2 ) n'-N (Rd) (R e ) (XIV)
    Formula in which:
    - Y ”represents the group -COOH, -COOZ”, -CFECH (OH) SO 3 H or the group CH 2 CH (OH) SO 3 -Z ”;
    - Ra and R e , independently of one another, represent a C1 to C4 alkyl or hydroxyalkyl radical;
    - Z ”represents a cationic counter ion derived from an alkali or alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine;
    - R a ”represents a Cio to C 3 o alkyl or alkenyl group of an acid R a ” -COOH preferably present in coconut oil or in hydrolysed linseed oil;
    - n and n ’, independently of each other, denote an integer ranging from 1 to 3.
    Among the compounds of formula (XII), mention may be made of the compound classified in the CTFA dictionary under the name sodium diethylaminopropyl cocoaspartamide and marketed by the company CHIMEX under the name CHIMEXANE HB.
    These compounds can be used alone or in mixtures.
    Among the amphoteric or zwitterionic surfactants mentioned above, use is preferably made of alkyl (C8-C2o) betaines such as cocobetaine, alkyl (C8-C2o) amidoalkyl (C 3 -C8) betaines such as cocamidopropylbetaine, and mixtures thereof, the compounds of formula (XIV) such as the sodium salt of lauryl amino diethylaminopropyl succinamate (INCI name sodium diethylaminopropyl cocoaspartamide).
    Preferably, the amphoteric or zwitterionic surfactants are chosen from alkyl (C8-C2o) amidoalkyl (C3Csjbétaines such as cocamidopropylbétaïne.
    The amphoteric or zwitterionic surfactant (s) generally represent from 0.1 to 20% by weight, preferably from 1 to 15%, more preferably from 2 to 10% by weight, and better still from 3 to 8% by weight, relative to the total weight of the composition according to the invention.
    According to a first preferred embodiment, the composition according to the invention does not comprise a cationic surfactant.
    According to a second preferred embodiment, the composition according to the invention does not comprise fatty alcohol.
    In a particularly preferred manner, the composition according to the invention does not comprise either cationic surfactant or fatty alcohol.
    The composition according to these two preferred embodiments has the advantage of not "charging" the hair and therefore brings lightness, volume and a natural, non-greasy appearance to the hair.
    As described above, the composition according to the invention comprises a cosmetically acceptable medium.
    The term “cosmetically acceptable medium” within the meaning of the present invention means a medium compatible with the hair and the scalp.
    Thus, the composition according to the invention may comprise water or a mixture of water and one or more cosmetically acceptable solvents chosen from lower C1C4 alcohols, such as ethanol, isopropanol, tertiary butanol or n-butanol; polyols such as glycerol, propylene glycol and polyethylene glycols; and their mixtures.
    Preferably, the composition according to the invention has a total water content of between 40 and 95% by weight, preferably between 50 and 90%, preferably between 60 and 85% by weight relative to the total weight of the composition.
    The pH of the compositions according to the invention generally varies from 3 to 8 and preferably from 3.5 to 6, better still from 4 to 5.5.
    The composition according to the invention can also comprise one or more conventional additives well known in the art, such as thickeners or viscosity regulators, natural or synthetic, different from the cationic polymers described above; ceramides; silicones; fatty esters such as isopropyl myristate, myristyl myristate, cetyl palmitate and stearyl stearate; mineral, vegetable or synthetic oils such as oc-olefins or avocado oil, rapeseed oil, apricot kernel oil, camelina oil, petrolatum oil; vitamins or provitamins; amphoteric or anionic polymers; pH stabilizers, preservatives; dyes; perfumes.
    Those skilled in the art will take care to choose any additives and their quantity so that they do not harm the properties of the compositions of the present invention.
    These additives are generally present in the composition according to the invention in an amount ranging from 0 to 20% by weight relative to the total weight of the composition.
    Preferably, the cosmetic composition of the invention is transparent or translucent, that is to say that this composition has a transmittance at 600 nanometers greater than 85%, better still greater than 90% and even better still greater than 94%.
    In particular, the composition according to the invention can be characterized from the measurement of its transmittance using a CARY 100 model spectrophotometer from the company Varian, at ambient temperature (25 ° C.), at a length d 700 nm wave.
    The present invention also relates to a cosmetic treatment process for keratin fibers, in particular human keratin fibers such as the hair, using said composition.
    This process consists in applying the composition according to the invention to dry or wet keratin fibers, which may have been washed with a shampoo.
    Preferably, the composition according to the invention is applied to wet keratin fibers.
    After a possible exposure time, the keratin fibers are optionally rinsed with water, possibly subjected to washing with a shampoo followed by rinsing with water, before being dried or left to dry.
    The composition according to the present invention is generally applied while respecting an exposure time which can range from 1 to 15 minutes, preferably from 2 to 10 minutes.
    Thus, the composition according to the invention can be used before a shampoo (as a pre-shampoo) or as a treatment preferably to be rinsed off after a shampoo (as a conditioner).
    Finally, the present invention relates to the use of said composition for the cosmetic treatment of keratin fibers, in particular human keratin fibers such as the hair, in particular for conditioning the keratin fibers or giving the keratin fibers a cosmetic treatment, such as detangling, remanent to shampoos.
    The following examples serve to illustrate the invention without, however, being limiting in nature.
    Example 1
    Composition A is prepared according to the invention from the 5 ingredients indicated in the table below, the amounts of which are expressed by weight of active material (MA) relative to the total weight of the composition.
    Ingredients A (Inv.) Laureth-5 carboxylic acid 6.3 Cocamidopropyl betaine 3.8 Laureth-4 5 3-Aminopropyl triethoxysilane 2 Polyquaternium-6 1.8 NaCl 1.2 Lactic acid 0.72 Preservatives qs PH agents Qs pH 5 Water Qs 100
    A composition is obtained which can be used as a conditioner.
    This composition according to the invention is compared with a commercial conditioner B, not comprising silane.
    Application protocol on locks of hair
    - Wash the locks with a DOP shampoo at the rate of 0.4 g per gram of lock of hair,
    - Rinsing with water,
    - Application of composition A or comparative B at a rate of 0.4 g per gram of lock of hair,
    - Installation of 5 min,
    - Rinsing with water,
    - Evaluation of wet hair strands
    The performances in terms of disentangling are evaluated at T0 after application of compositions A or B and rinsing as described above, then after 1, 3 and 5 washes with the DOP shampoo and rinsing (possible evaluations: very good, good, medium, bad, very bad).
    Results
    Detangle A (Inv.) B (Comp.) T0 very good very good After 1 shampoo very good bad After 3 shampoos very good very bad After 5 shampoos Well very bad
    The composition A according to the invention makes it possible to have as good a level of disentangling on the first application as the comparative composition B (commercial rinsed conditioner).
    However, the disentangling is persistent after 5 shampoos for composition A, unlike comparative composition B.
    Example 2
    Composition C is prepared according to the invention and comparative composition D from the ingredients indicated in the table below, the amounts of which are expressed by weight of active material relative to the total weight of the composition.
    Ingredients C (Inv) D (Comp) Laureth-5 carboxylic acid 6.3 Cocamidopropyl betaine 3.8 Laureth-4 5 Polysorbate 20 5 3-Aminopropyl triethoxysilane 5 5 Polyquaternium-6 2.4 0.48 NaCl 1.2 - Lactic acid - 1.8 Amodimethicone - 1.5 Cetrimonium chloride - 0.65 Behentrimonium chloride - 0.47 Dipalmitoylethylhydroxyethylmonium methosulfate - 0.3 Cetearyl alcohol - 0.7 Myristic alcohol - 0.4 Cetyl alcohol - 8 Isopropylic alcohol - 0.1 Mixture of myristyle stearate and myristyle palmitate - 1 Trideceth-6 - 0.13 Hydroxyethyl cellulose - 0.25 PH agents Qs pH 5 Qs pH 5 Preservatives Qs Qs Water Qs 100 Qs 100
    The locks of hair are treated with compositions C and D according to the protocol described above.
    Easy combing tests on damp hair were performed using a Lloyd LR5K compression pulling machine.
    The wick is fixed at its end, on the root side, and is free on the tip side. At constant speed, we measure the force exerted to allow the passage of a fine comb through damp hair: the force is all the weaker as the hair is easy to comb.
    These measurements are carried out at TO, then after 2, 4 and 8 shampoos as described above.
    The measurements are carried out on 6 wicks each time. The following are the averages of the forces (work W) measured (in arbitrary units).
    Combing C (Inv.) D (Comp.) TO 26 ± 3 221 ± 90 After 2 shampoos 25 ± 1 523 ± 245 After 4 shampoos 27 ± 2 1645 ± 428 After 8 shampoos 30 ± 2 1406 ± 270
    The composition according to the invention C has significantly lower combing forces compared to the comparative composition D: the combing is significantly easier.
    In addition, the performances as regards the ease of combing of the composition according to the invention C are persistent up to 8 shampoos, in contrast to the comparative composition D.
    Example 3
    Formulation of compositions
    The compositions E and F according to the invention and the comparative composition G are prepared from the ingredients indicated in the table below, the amounts of which are expressed by weight of active material relative to the total weight of the composition.
    Ingredients E (Inv.) F (Inv.) G(Comp.) Laureth-5 acidcarboxylic 6.3 6.3 - Sodium laureth sulfate - 1.75 - Cocamidopropyl betaine 3.8 3.8 Laureth-4 5 5 - Polysorbate 20 5 5 - 3-Aminopropyltriethoxysilane 5 5 5 Polyquaternium-6 0.48 0.48 0.48 NaCl 1.2 1.2 - PH agents Qs pH 5 Qs pH 5 Qs pH 5 conservatives Qs Qs Qs Water Qs 100 Qs 100 Qs 100
    Application protocol
    - Washing of locks of hair using a DOP shampoo at the rate of 0.4 g per gram of lock of hair,
    - Rinsing with water,
    - Application of composition E to G at a rate of 0.4 g per gram of lock of hair,
    - Installation of 5 min.
    - Rinsing with water,
    - Evaluation of wet hair strands
    The polyquaternium-6 deposit is measured on the locks of hair.
    The deposition of polyquaternium-6 is determined by gel electrophoresis after acid dissolution of the hair. Two measurements are made each time.
    Results
    This table indicates the average cationic polymer contents of the locks of hair (expressed in pg / g of hair) and the standard deviations of these measurements.
    Cationic polymer content E (Inv.) F (Inv.) G(Comp.) T0 238 138 120 Standard deviation 11 4 7 After 3 shampoos 143 68 <LQ Standard deviation 4 4 - After 5 shampoos 123 60 <LQ Standard deviation 4 - -
    "<LQ" indicates that the quantities of cationic polymers are too low to be detected (quantifiable limit).
    The compositions according to the invention E and F make it possible to deposit a larger amount of cationic polymer at T0 compared to the comparative composition G
    These results also show that the compositions according to the invention E and F make it possible to deposit cationic polymers on the surface of the hair retentively with at least 5 shampoos. On the contrary, the hair treated with the comparative composition G no longer comprises on its surface enough cationic polymers even after only 3 shampoos.
    Thus, this residual deposit, in particular of cationic polymers, guarantees the care properties such as the disentangling of the hair treated with the compositions according to the invention.
    权利要求:
    Claims (20)
    [1" id="c-fr-0001]
    1. Cosmetic composition for the treatment of keratin fibers, in particular human keratin fibers such as the hair, comprising in a cosmetically acceptable medium:
    (i) one or more organosilanes, (ii) one or more cationic polymers, (iii) one or more anionic surfactants, (iv) one or more nonionic surfactants, and (v) one or more amphoteric or zwitterionic surfactants, weight ratio of the total amount of the anionic surfactant (s) to the total amount of the nonionic surfactant (s) being less than or equal to 5.
    [2" id="c-fr-0002]
    2. Composition according to claim 1, characterized in that the organosilane (s) are chosen from the compounds of formula (I) and / or their hydrolysis products and / or their oligomers:
    RiSi (OR 2 ) z (R3) x (OH) y (I) in which
    - Ri is a C 1 to C 22 , in particular C 2 to C 2 o hydrocarbon chain, linear or branched, saturated or unsaturated, cyclic or acyclic, which can be substituted by one or more group (s) chosen from amine groups NH 2 or NHR with R being a linear or branched Ci to C 2 o, in particular Ci-alkyl, or a C3-C40 aromatic radical or a cO-C30; the hydroxy group; a thiol group; an aryl group, more particularly benzyl, substituted or not substituted by an NH 2 or NHR group; Ri can be interrupted by a heteroatom of oxygen, sulfur or nitrogen or a carbonyl group;
    - R 2 and R3, identical or different, represent an alkyl group, linear or branched, comprising from 1 to 6 carbon atoms,
    - y denotes an integer ranging from 0 to 3,
    - z denotes an integer ranging from 0 to 3, and
    - x denotes an integer ranging from 0 to 2,
    - with z + x + y = 3.
    [3" id="c-fr-0003]
    3. Composition according to claim 2, characterized in that the organosilane (s) are chosen from the compounds of formula (I) in which R 1 represents a linear alkyl group comprising from 7 to 18 carbon atoms and more particularly from 7 to 12 atoms carbon or a C1-C6, preferably C2-C4 aminoalkyl group, and more preferably R1 represents an octyl group.
    [4" id="c-fr-0004]
    4. Composition according to claim 2, characterized in that the organosilane (s) are chosen from the compounds of formula (I) in which R 1 is a C 1 to C 22 hydrocarbon chain, linear or branched, saturated or unsaturated, substituted by one or several NH 2 or NHR amine group (s), R being a linear or branched C1 to C20 alkyl, in particular C1 to C6, or a C3 to C40 cycloalkyl or a C6 to C30 aromatic, and preferably R1 represents an aminoalkyl group in Ci to Cô, more preferably in C2 to C4.
    [5" id="c-fr-0005]
    5. Composition according to any one of the preceding claims, characterized in that the organosilane (s) are chosen from octyltriethoxysilane (OTES), dodecyltriethoxysilane, octadecyltriethoxysilane, hexadecyltriethoxysilane, 3 aminopropyltriethoxysilane (2- ATS), 2- aminoethyltriethoxysilane (AETES), 3-aminopropylmethyldiethoxysilane, N- (2-aminoethyl) 3-aminopropyltriethoxysilane, 3- (maminophenoxy) propyltrimethoxysilane, paminophenyltrimethoxysilane, N- (2-ethylethylinomethylane ethoxysimanes), their mixtures; and preferably the organosilane (s) are chosen from octyltriethoxysilane (OTES), 3-aminopropyltriethoxysilane (APTES), their hydrolysis products, their oligomers and their mixtures, and more preferably the organosilane is 3-aminopropyltriethoxysilane (APTES) ).
    [6" id="c-fr-0006]
    6. Composition according to any one of the preceding claims, characterized in that the organosilane (s) represent from 0.1 to 15% by weight, preferably from 0.5 to 10% by weight, and more preferably from 1 to 8 % by weight, relative to the total weight of the composition.
    [7" id="c-fr-0007]
    7. Composition according to any one of the preceding claims, characterized in that the cationic polymer (s)
    5 are chosen from:
    (1) homopolymers or copolymers derived from acrylic or methacrylic esters or amides and comprising at least one of the units of formulas (II), (III), (IV) or (V):
    (ΠΙ)
    CHj
    NH
    AI + (IV) (V) in which:
    R3, identical or different, denote a hydrogen atom or a CH3 radical;
    A, identical or different, represent an alkyl group, linear or branched, from 1 to 6 carbon atoms, preferably from 2 or 3 carbon atoms or a hydroxyalkyl group from 1 to 4 carbon atoms:
    R.4, R5, R6, identical or different, represent an alkyl group having from 1 to 18 carbon atoms or a benzyl radical and preferably an alkyl group having from 1 to 6 carbon atoms;
    Ri and R2, identical or different, represent a hydrogen atom or an alkyl group having from 1 to 6 carbon atoms and preferably a methyl or ethyl radical;
    X denotes an anion derived from a mineral or organic acid such as a methosulfate anion or a halide such as chloride or bromide, (2) derivatives of cellulose ethers containing quaternary ammonium groups, (3) cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer, (4) cationic guar gums, (5) polymers consisting of piperazinyl units and divalent alkylene or hydroxyalkylene radicals with straight or branched chains, optionally interrupted by oxygen, sulfur, nitrogen atoms or by aromatic or heterocyclic rings, as well as the oxidation and / or quaternization products of these polymers,
    (6) the polyaminoamides soluble in the water prepared in particular by polycondensation of a compound acid with a polyamine, (Ό the polyaminoamide derivatives resulting of the condensation of polyalkylenes polyamines with of acids polycarbox yliques followed by alkylation by of agents
    bifunctional, (8) polymers obtained by reaction of a polyalkylene polyamine comprising two primary amine groups and at least one secondary amine group with a dicarboxylic acid chosen from diglycolic acid and saturated aliphatic dicarboxylic acids having from 3 to 8 atoms carbon, the molar ratio between the polyalkylene polylamine and the dicarboxylic acid being between 0.8: 1 and 1.4: 1 and the resulting polyaminoamide being reacted with epichlorohydrin in a molar ratio of epichlorohydrin relative to the secondary amine group of the polyaminoamide of between 0.5: 1 and 1.8: 1, (9) cyclopolymers of alkyl diallyl amine or of dialkyl diallyl ammonium such as homopolymers or copolymers comprising as main constituent of the chain of units corresponding to formulas (VI) or (VII):
    CH
    H.
    (VI) / (ÇH 2 ) k
    Ç (R g ) - CH r
    R.
    ‘7
    CH.
    (VII) formulas in which:
    k and t are equal to 0 or 1, the sum k + t being equal to 1;
    R9 denotes a hydrogen atom or a methyl radical;
    R7 and Rs, independently of one another, denote an alkyl group having from 1 to 6 carbon atoms, a hydroxyalkyl group in which the alkyl group preferably has 1 to 5 carbon atoms, a lower amidoalkyl group (C1 -C4), or R7 and Rs can denote jointly with the nitrogen atom to which they are attached, heterocyclic groups, such as piperidinyl or morpholinyl; R7 and Rs, independently of one another, preferably denote an alkyl group having from 1 to 4 carbon atoms;
    Y is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, phosphate, (10) quaternary diammonium polymers containing recurring units corresponding to the following formula (VIII):
    R 10 R 12 - N + -A 1 —Ν + -Β ή -
    R- | - | X R-13 X (wine) in which:
    Rio, Ru, R12 and R13, identical or different, represent aliphatic, alicyclic, or arylaliphatic radicals containing from 1 to 6 carbon atoms or lower hydroxyalkylaliphatic radicals, or else Rio, Ru, R12 and R13, together or separately, constitute with the nitrogen atoms to which they are attached heterocycles optionally containing a second heteroatom other than nitrogen or else Rio, R11, R12 and R13 represent a linear or branched C1-C6 alkyl radical substituted by a nitrile, ester group, acyl, amide or -CO-O-R14-D or -CO-NH-R14-D where R14 is an alkylene and D is a quaternary ammonium group;
    Ai and Bi represent polymethylenic groups containing from 2 to 8 carbon atoms which may be linear or branched, saturated or unsaturated, and which may contain, linked to or intercalated in the main chain, one or more aromatic rings, or one or more atoms of oxygen, sulfur or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups, and
    X denotes an anion derived from a mineral or organic acid;
    Ai, Rio and R12 can form with the two nitrogen atoms to which they are attached a piperazine ring; in addition, if Ai denotes a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene radical, Bi can also denote a group - (CH 2 ) „- CO-D-OC- (CH 2 )„ - in which D denotes:
    a) a glycol residue of formula: -O-Z-O-, where Z denotes a linear or branched hydrocarbon radical or a group corresponding to one of the following formulas:
    - (CH 2 -CH 2 -O) x-CH 2 -CH 2 3060381
    - [CH2-CH (CH 3 ) -O] y -CH 2 -CH (CH3) where x and y denote an integer from 1 to 4, representing a defined and unique degree of polymerization or any number from 1 to 4 representing an average degree of polymerization;
    b) a bis-secondary diamine residue such as a piperazine derivative;
    c) a bis-primary diamine residue of formula: -NH-Y-NH-, where Y denotes a linear or branched hydrocarbon radical, or else the bivalent radical
    -CH2-CH2-S-S-CH2-CH2-;
    d) a ureylene group of formula: -NH-CO-NH-, (11) quaternary polyammoniums consisting of recurring units of formula (X):
    CH,
    CH,
    --N - (CH 2 ) -NH-CO-D-NH - (CH 2 ) p - N - (CH 2 ) 2 - O - (CH 2 ) 2 -
    CH,
    CH, (X) in which p denotes an integer varying from 1 to 6 approximately, D may be zero or may represent a group - (CH 2 ) rCO- in which r denotes a number equal to 4 or 7, X is an anion, (12) quaternary polymers of vinylpyrrolidone and vinylimidazole, (13) cationic polyamines.
    [8" id="c-fr-0008]
    8. Composition according to Claim 7, characterized in that the cationic polymer (s) are chosen from polymers of the families (1), (2), (3), (4), (9), (10) and (12 ), more particularly among the polymers of families (2) and (9), and better among the polymers of family (9).
    [9" id="c-fr-0009]
    9. Composition according to any one of the preceding claims, characterized in that the cationic polymer (s) represent from 0.01 to 10% by weight, preferably from 0.1 to 8% by weight, more preferably from 0.2 to 5% by weight and even better from 0.3 to 3.5% by weight, relative to the total weight of the composition.
    [10" id="c-fr-0010]
    10. Composition according to any one of the preceding claims, characterized in that the anionic surfactant (s) are chosen from anionic surfactants comprising in their structure one or more sulphate and / or sulphonate and / or phosphate and / or carboxylate groups, and / or their mixtures, preferably the anionic surfactant (s) are chosen from anionic surfactants comprising in their structure one or more sulphate and / or sulphonate and / or phosphate groups, the anionic alkyl ether carboxylic surfactants and / or their mixtures, and more preferably the anionic surfactant (s) are chosen from anionic alkyl ether carboxylic surfactants.
    [11" id="c-fr-0011]
    11. Composition according to Claim 10, characterized in that the anionic surfactants comprising in their structure one or more sulphate and / or sulphonate groups and / or phosphates are chosen from alkyl sulphates, alkylamidosulphates, alkyl ether sulphates, alkylamidoethersulphates, alkylarylethersulfates, alkylethersulfosuccinates, acyl isethionates, methyl acyl taurates, olefin sulfonates and their salts; the alkyl or acyl group of all these different compounds preferably comprising from 8 to 24 carbon atoms, and the aryl group preferably denoting a phenyl or benzyl group.
    [12" id="c-fr-0012]
    12. Composition according to claim 10, characterized in that the anionic alkyl ether carboxylic anionic surfactant (s) are chosen from the polyethoxylated anionic carboxylic surfactants of formula (XI):
    Ri (OC 2 H 4 ) nOCH 2 COOA (XI) in which:
    Ri represents a group or a mixture of alkyl or alkenyl groups, linear or branched, in Cs-C 22 , an alkyl group (CsCQphenyl, a group R 2 CONH-CH 2 -CH 2 - with R 2 denoting an alkyl or alkenyl group , linear or branched, in C11-C21, n is an integer or decimal number which can vary from 2 to 24 and preferably from 2 to 15,
    A denotes H, NTU, Na, K, Li, Mg or a monoethanolamine or triethanolamine residue.
    [13" id="c-fr-0013]
    13. Composition according to any one of the preceding claims, characterized in that the anionic surfactant (s) represent from 1 to 20% by weight, preferably from 2 to 18% by weight, more preferably from 4 to 15% by weight, relative the total weight of the composition.
    [14" id="c-fr-0014]
    14. Composition according to any one of the preceding claims, characterized in that the nonionic surfactant (s) are chosen from:
    - Cs to C40 alcohols, saturated or unsaturated, linear or branched, oxyethylenated comprising from 1 to 100 moles of ethylene oxide, preferably from 2 to 50, more particularly from 2 to 40 moles of ethylene oxide and comprising one or two fatty chains;
    oxyethylenated vegetable oils, saturated or not, comprising from 1 to 100 moles of ethylene oxide, preferably from 2 to 50;
    (C8-C3o) alkyl (poly) glucosides, optionally oxyalkylenated, preferably from 0 to 10 moles of ethylene oxide, and comprising 1 to 15 glucose units;
    - Cs to C40 alcohols, mono- or polyglycerolated, comprising from 1 to 50 moles of glycerol, preferably from 1 to 10 moles of glycerol;
    - fatty acid amides of Cs to C30, saturated or unsaturated, linear or branched, oxyalkylenated;
    - esters of Cs to C30 acids, saturated or not, linear or branched, and of polyethylene glycols;
    - esters of Cs to C30 acids, saturated or unsaturated, linear or branched, and preferably oxyethylenated sorbitol, and their mixtures.
    [15" id="c-fr-0015]
    15. Composition according to any one of the preceding claims, characterized in that the non-ionic surfactant (s) are chosen from:
    - Cs to C40 alcohols, saturated or unsaturated, linear or branched, oxyethylenated comprising from 1 to 100 moles of ethylene oxide, preferably from 2 to 50, more particularly from 2 to 40 moles of ethylene oxide and comprising one or two fatty chains;
    - the esters of Cs to C30 acids, saturated or not, linear or branched, and preferably oxyethylenated sorbitol, preferably the nonionic surfactant (s) are chosen from:
    - Cs to C40 alcohols, saturated or unsaturated, linear or branched, oxyethylenated comprising from 1 to 100 moles of ethylene oxide, preferably from 2 to 50, more particularly from 2 to 40 moles of ethylene oxide and comprising one or two fatty chains.
    [16" id="c-fr-0016]
    16. Composition according to any one of the preceding claims, characterized in that the nonionic surfactant (s) represent from 2 to 20% by weight, preferably from 3 to 15% by weight, and more preferably from 4 to 12% by weight relative to the total weight of the composition.
    [17" id="c-fr-0017]
    17. Composition according to any one of the preceding claims, characterized in that the amphoteric or zwitterionic surfactant (s) are chosen from alkyl (C8-C 2 o) betaines, alkyl (C8-C 2 o) sulfobetaines, alkyl (C8-C 2 o) amidoalkyl (C3Csjbétaines and alkyl (C8-C 2 o) amidalkyl (C6-C8) sulfobetaines.
    [18" id="c-fr-0018]
    18. Composition according to any one of the preceding claims, characterized in that the amphoteric or zwitterionic surfactant (s) represent from 0.1 to 20% by weight, preferably from 1 to 15%, more preferably from 2 to 10% by weight. weight, and better still from 3 to 8% by weight, relative to the total weight of the composition.
    [19" id="c-fr-0019]
    19. Method for the cosmetic treatment of keratin fibers, in particular human keratin fibers such as the hair, using the composition as defined in any one of claims 1 to 18.
    [20" id="c-fr-0020]
    20. Use of the composition as defined in any one of claims 1 to 18 for the cosmetic treatment of keratin fibers, in particular human keratin fibers such as the hair, in particular for conditioning the fibers
    5 keratin or give the keratin fibers a cosmetic treatment, such as detangling, which remains in shampoos.
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    法律状态:
    2017-11-13| PLFP| Fee payment|Year of fee payment: 2 |
    2018-06-22| PLSC| Publication of the preliminary search report|Effective date: 20180622 |
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    申请号 | 申请日 | 专利标题
    FR1662659|2016-12-16|
    FR1662659A|FR3060381B1|2016-12-16|2016-12-16|COSMETIC COMPOSITION COMPRISING AN ORGANOSILANE, AT LEAST ONE CATIONIC POLYMER AND A PARTICULAR ASSOCIATION OF SURFACTANTS|FR1662659A| FR3060381B1|2016-12-16|2016-12-16|COSMETIC COMPOSITION COMPRISING AN ORGANOSILANE, AT LEAST ONE CATIONIC POLYMER AND A PARTICULAR ASSOCIATION OF SURFACTANTS|
    PCT/EP2017/082435| WO2018108919A1|2016-12-16|2017-12-12|Cosmetic composition comprising an organosilane, at least one cationic polymer and a particular combination of surfactants|
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